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71.
72.
Many base load onshore LNG plants use large number of Air-Fin-Coolers normally mounted on the center pipe rack of the LNG process train. Further, the LNG plant modularized approach requires large, complex structures (modules) for supporting the LNG process equipment and for allowing sea and land transportation. This results in additional congestion of the plant and large voids under module-deck, which are confined by large girders. Thus, in case of leaks, the proper ventilation to reduce the accumulation of gas is critical for the safety of the plant.This paper evaluates the Air-Fin-Cooler induced air flow in modularized LNG plants using Computational Fluid Dynamics (CFD) analysis.The results of this evaluation show that the ventilation of the Air-Fin-Cooler induced air flow is influenced by the process train orientation. Further, a moderate increase is observed in specific design conditions or areas, such as shorter separation distances between modules. Based on the results of this evaluation, four design measures are proposed to optimize the use of Air-Fin-Cooler, such as train orientation against prevailing wind direction and use of the grating deck material. 相似文献
73.
Kazuhiro Okabe Hiroshi Mano Yuichi Fujioka 《International Journal of Greenhouse Gas Control》2010,4(4):597-602
The membrane flash process utilizing waste thermal energy was developed to achieve an energy-saving technology and to substitute it for a conventional regenerator. The operating conditions of the membrane flash at high temperature were studied. The petroleum refining process and iron manufacturing process were proposed for candidate processes that actually had waste energy sources. The DEA concentration and the flashing pressure had optimum values to improve the performance and reduce the energy consumption for CO2 recovery. Energy consumptions and costs for CO2 recovery in the membrane flash and chemical absorption were estimated by a process simulator and discussed under the same conditions. The membrane flash can achieve lower energy capture than the chemical absorption for the above industrial processes. The membrane flash is suitable for the CO2 emission sources that had high CO2 concentration independently of the plant scale. The chemical absorption can be applied if the plant scale is large and also the CO2 concentration is low. 相似文献
74.
Vinay Kumar Jha Masahiro Nagae Motohide MatsudaMichihiro Miyake 《Journal of environmental management》2009
Zeolitic materials have been prepared from coal fly ash as well as from a SiO2–Al2O3 system upon NaOH fusion treatment, followed by subsequent hydrothermal processing at various NaOH concentrations and reaction times. During the preparation process, the starting material initially decomposed to an amorphous form, and the nucleation process of the zeolite began. The carbon content of the starting material influenced the formation of the zeolite by providing an active surface for nucleation. Zeolite A (Na-A) was transformed into zeolite X (Na-X) with increasing NaOH concentration and reaction time. The adsorption isotherms of the obtained Na-X based on the characteristics required to remove heavy ions such as Ni2+, Cu2+, Cd2+ and Pb2+ were examined in multi-metal systems. Thus obtained experimental data suggests that the Langmuir and Freundlich models are more accurate compared to the Dubinin–Kaganer–Radushkevich (DKR) model. However, the sorption energy obtained from the DKR model was helpful in elucidating the mechanism of the sorption process. Further, in going from a single- to multi-metal system, the degree of fitting for the Freundlich model compared with the Langmuir model was favored due to its basic assumption of a heterogeneity factor. The Extended-Langmuir model may be used in multi-metal systems, but gives a lower value for equilibrium sorption compared with the Langmuir model. 相似文献
75.
Persistent organic pollutants have been shown to have immunomodulating effects in humans. However, epidemiological evidence regarding the relationships between organochlorine compound exposure and allergic disorders coming from studies of children has been limited and inconsistent. The current cross-sectional study examined the associations between the concentrations of β-hexachlorocyclohexane (HCH), hexachlorobenzene (HCB), p,p'-dichlorodiphenyldichloroethylene (DDE), and trans-nonachlordane in breast milk and the prevalence of allergic disorders in 124 adult Japanese women. The definition of wheeze and asthma was based on criteria from the European Community Respiratory Health Survey whereas that of eczema and rhinoconjunctivitis was based on criteria from the International Study of Asthma and Allergies in Childhood. Adjustment was made for age, smoking, family history of allergic disorders, and education. The prevalence values of wheeze, asthma, eczema, and rhinoconjunctivitis in the past 12 months were 9.7%, 4.8%, 13.7%, and 29.8%, respectively. The median concentrations of β-HCH, HCB, p,p'-DDE, and trans-nonachlordane in breast milk were 28.3, 7.0, 71.6, and 23.9 ng g(-1) lipid, respectively (range, 4.5-253, 2.1-14.5, 7.5-362, and 1.8-130 ng g(-1) lipid, respectively). When the exposures were treated as continuous variables, no significant associations were found between concentrations of HCB, β-HCH, p,p'-DDE, or trans-nonachlordane and the prevalence of wheeze, asthma, eczema, or rhinoconjunctivitis. Our results suggest that concentrations of β-HCH, HCB, p,p'-DDE, and trans-nonachlordane in breast milk are not evidently associated with the prevalence of wheeze, asthma, eczema, or rhinoconjunctivitis in young female Japanese adults. 相似文献
76.
Atsumi Miyake Hidefumi Kobayashi Hiroshi Echigoya Shiro Kubota Yuji Wada Yuji Ogata Hiroyuki Arai Terushige Ogawa 《Journal of Loss Prevention in the Process Industries》2007,20(4-6):584-588
To better understand the detonation characteristics of ammonium nitrate (AN) and activated carbon (AC) mixtures, steel tube tests were carried out for AN/AC mixtures of various compositions and different forms of AN (powdered, prilled, phase stabilized and granular), and the detonation velocity was measured. The powdered AN/AC mixtures gave higher detonation velocities than the other AN forms. For all the AN/AC mixtures, the experimentally observed detonation velocities at each loading density were far below the theoretically predicted values calculated by the CHEETAH code based on thermohydrodynamics, exhibiting so-called non-ideal detonation. The lowest detonation velocity of powdered AN/AC mixtures was obtained as D=1.25 km/s for an AC content of 0.1 wt%. This was considered to be close to the critical condition for stable detonation. 相似文献
77.
Kazuya Goto Hiromichi Okabe Firoz Alam Chowdhury Shinkichi Shimizu Yuichi Fujioka Masami Onoda 《International Journal of Greenhouse Gas Control》2011,5(5):1214-1219
In order to establish energy-saving technology for CO2 capture from blast furnace gas, novel absorbents were developed in the laboratory and evaluated at a 1 tCO2/d test plant. At first, CO2 absorption and desorption behaviors of single-component amine solvents for simulated blast furnace gas (CO2/N2 = 20%/80%) were investigated through a screening test using a small scrubbing bottle. These amine solvents were additionally analyzed using nuclear magnetic resonance (13C NMR) spectroscopy and reaction calorimetry. The results of the laboratory experiments showed that there was a trade-off between absorption rate and enthalpy of absorption but some absorbents had unique features. For example, 2-isopropylaminoethanol (IPAE) had high absorption rate and small enthalpy of absorption. Then, new IPAE-based amine solvents (RITE solvents: RITE-A and RITE-B) were formulated and evaluated at the 1 tCO2/d test plant. CO2 regeneration energies of the RITE solvents were 3.3 and 3.1 GJ/tCO2, respectively. With certain process conditions and plant specifications optimized, RITE-B was estimated to have the potential to achieve 2.5 GJ/tCO2. 相似文献